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Lithium tri-sec-butylborohydride

Lithium tri-sec-butylborohydride

SKU: 364215376135191

CAS NO.:38721-52-7
Molecular formula:Li(C4H9)3BH
Molecular weight:190.11


Quality index

Appearance

Quality Index

Colorless or light grey liquid

Concentration: 1±0.02M in THF

 

Properties
This product is a strong reducing agent and it has very high stereoselectivity. Flash point :-17℃.

 

Usage
This product is a high stereoselective reducing agent. It has been used for the diastereoselective reduction of the ketones to give the alcohol. It can be also used for selective 1,4- addition of the enones to provide ketones or alcohols. It is used for selective reduction of the conjugated double bonds of cyclic acrylonitrile derivatives and iodide. It was also found to be an efficient reagent for the mesomerize reaction of diesters, dehalogenation of monocyclic Pyrimidine, rearrangement of 5-trimethylsilyl Thebaine, and deprotection of N-carbomethoxy-substituted opioids to N-noropioids. At low temperatures, it can effectively reduce conjugated carbonyl compounds.

 

Packing
100ml/Glass bottle; 500ml/Glass bottle; 1L/Glass bottle; 60L/Stainless steel barrel; 70L/Stainless steel barrel; 100L/Stainless steel barrel.
 

Storage
Avoid breakage and moisture, far away from heat, fire and inflammable matter, no mix with acid, oxidant and substance containing water. Stored in a sealed container and kept in cool, dry and well-ventilating chemical warehouse.
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